{Fe6O2}-Based Assembly of a Tetradecanuclear Iron Nanocluster

نویسندگان

  • Svetlana G. Baca
  • Manfred Speldrich
  • Arkady Ellern
  • Paul Kögerler
چکیده

The tetradecanuclear FeIII pivalate nanocluster [Fe14O10(OH)₄(Piv)18], comprising a new type of metal oxide framework, has been solvothermally synthesized from a hexanuclear iron pivalate precursor in dichlormethane/acetonitrile solution. Magnetic measurements indicate the presence of very strong antiferromagnetic interactions in the cluster core.

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عنوان ژورنال:

دوره 4  شماره 

صفحات  -

تاریخ انتشار 2011